ELECTROCHEMICAL DEGRADATION OF REMAZOL RED RB 133 USING SACRIFICIAL ELECTRODES

Authors

  • H. B. Rekha Assistant Professor, Department of Civil Engineering, Bangalore University, Bangalore-560-056
  • Usha N. Murthy Professor, Department of Civil Engineering, Bangalore University, Bangalore-560-056

DOI:

https://doi.org/10.20319/mijst.2018.41.106128

Keywords:

Aluminum, Electro-Coagulation, Reactive Red, Iron

Abstract

Textile industries generate various types of wastewater depending on the industrial process and the raw materials used such as jute, cotton and animal fibers (wool and silk) and synthetic materials (nylon, polyester and acrylic). Dyeing and printing unit in textile processing industries use large volume of water (ranging from 200 to 250 kilo liter per ton of textiles) and different chemicals, dyes, and complex organic compounds make the textile wastewater very complicated to treat. In recent years, an alternative method to the conventional ones is the Electrochemical Treatment based on the generation of very reactive species such as hydroxyl radicals that oxidize a broad range of organic pollutants non-selectivity and quickly. The study aimed at the degradation of reactive dye by electro-coagulation using iron and aluminium electrodes.The results showed maximum color removal of 90.59% and COD removal of 54.36% operating at a current density of 176 A/m2 after electrolysis duration of 10 minutes at optimum pH 7 for iron electrode. Aluminum electrodes showed maximum color removal of 72.33% and COD removal of 56% after an electrolysis duration of 60 minutes, pH 7 at a current density of 216 A/m2. At the optimum conditions, the energy consumption, electrode consumption and operating cost to treat a cubic meter of sample found to be less for iron than aluminium electrode. The study concluded that, electro-coagulation proved to be an efficient method for the degradation of reactive red dye using iron electrode.

References

APHA (2012), “Standard methods for the examination of water and wastewater”, 22th edition, American Public Health Association, Washington D C.

Basiri Parsa J, Rezaei M, Soleymani A.R (2009), “Electrochemical Oxidation of an Azo Dye in Aqueous Media Investigation of Operational Parameters and Kinetics”, Journal of Hazardous Materials, Vol: 168, pp: 997–1003.

Bayramoglu, M., Kobya, M., Can, O.T., Sozbir, M., (2004), “Operating cost analysis of electrocoagulation of textile dye wastewater”, Sep. Purif. Technol. 37 (2), pp: 117–125.

Can O T, Bayramoglu M and Kobya Decolorization (2003), “Reactive Dye Solutions by Electrocoagulation Using Aluminum Electrodes” Ind. Eng. Chem. Res., Vol: 42, pp: 3391-3396.

Can O T, Kobya M, Demirbas E, Bayramoglu M, (2006), “Treatment of the Textile Wastewater by Combined Electrocoagulation”, Chemosphere, 62, pp: 181–187.

Chen Guoh (2004), “Electrochemical Technologies in Wastewater Treatment, Separation and Purification Technology”, Vol: 38, pp: 11–41.

Daneshvar N, Oladegaragoze, Djafarzadeh N (2006), “Decolorization of Basic Dye Solutions by Electrocoagulation: An Investigation of the Effect of Operational Parameters”, Journal of Hazardous Materials, B129, pp: 116–122.

Essadki A H, Bennajah M, Gourich B, Ch. Vial, Azzi M, Delmas H, (2008), “Electrocoagulation/electroflotation in an external-loop airlift reactor—Application to the decolorization of textile dye wastewater: A case study”,Chemical Engineering and Processing, 47, pp:1211–1223.

Ghaly AE, Ananthashankar R, Alhattab M, Ramakrishnan V V (2014), “Production, Characterization and Treatment of Textile Effluents: A Critical Review”, J Chem Eng Process Technol 5: 182. doi: 10.4172/2157- 7048.1000182.

Gupta V K, Khamparia S, Tyagi I, Jaspal D, Malviya A (2015), “Decolorization of Mixture of Dyes: A Critical Review”, Global J. Environ.Sci. Manage., Vol: 1 (1), pp: 71-94.

Hajira Khan, Nasir Ahmad, Abdullah Yasar and Rukhsana Shahid (2010), “Advanced Oxidative Decolorization of Red Cl-5B: Effects of Dye Concentration, Process Optimization and Reaction Kinetics”, Polish J. of Environ. Stud., Vol: 19, No: 1, pp: 83-92.

Jovic M, Dalibor Stankovic, Dragan Manojlovic, Ivan Andelkovic, Andelija Milic, Biljana Dojcinovic and Goran Roglic (2013), “Study of the Electrochemical Oxidation of Reactive Textile Dyes Using Platinum Electrode”, Int. J. Electrochem. Sci., Vol: 8, pp: 168 – 183.

Kobya M, Can O T, Bayramoglu M (2003), “Treatment of Textile Wastewaters by Electrocoagulation Using Iron and Aluminum Electrodes”, Journal of Hazardous Materials, B100, pp: 163–178.

Kobya M, Demirbas E and Akyol A (2009), “Electrochemical Treatment and Operating Cost Analysis of Textile Wastewater using Sacrificial Iron Electrodes”, Water Science & Technology, 60.9, pp: 2261-2270.

Krishna B M, (2012), “Electrochemical Pretreatment of Distillery Wastewater by Electrochemical Oxidation”, Ph.D Thesis submitted to Bangalore University, Bengaluru.

Mahmoud M S (2016), “Decolorization of Certain Reactive Dye from Aqueous Solution using Baker’s Yeast (Saccharomyces Cerevisiae) Strain”, HBRC journal, pp: 88–98.

Malpass G R P, Miwa D W, Machado S A S and Motheo A J (2008), “Decolorization of Real Textile Waste Using Electrochemical Techniques: Effect of Electrode Composition”, Journal of Hazardous Materials, Vol: 156, pp: 170–177.

Mariana Neamtua, Ayfer Yedilerb, Ilie Siminiceanua, Matei Macoveanua, Antonius Kettrupb, (2004), “Decolorization of Disperse Red 354 Azo Dye in Water by Several Oxidation Processes—A Comparative Study”, Dyes and Pigments, Vol 60, pp: 61–68.

Martı´nez-Huitle, Carlos A, Enric Brillas (2009), “Decontamination of Wastewaters Containing Synthetic Organic Dyes by Electrochemical Methods: A General Review”, Applied Catalysis B: Environmental, Vol: 87, pp: 105–145.

Mireia Sala and Carmen Guti´errez-Bouz´an (2012), “Electrochemical Techniques in Textile Processes and Wastewater Treatment”, Hindawi Publishing Corporation International Journal of Photo energy, Vol: 12, DOI: https://doi.org/10.1155/2012/629103

Mollaha M Y A, Jewel A.G. Gomesb, Kamol K. Dasc and David L. Cocke (2010),“Electrochemical Treatment of Orange II Dye Solution—Use of Aluminum Sacrificial Electrodes and Floc Characterization”, Journal of Hazardous Materials, Vol: 174, pp: 851–858.

Muthukumar, M.; Thalamadai Karuppiah, M.; Bhaskar Raju, G. (2007) Electrochemical removal of CI Acid orange 10 from aqueous solutions. Sep. Purif. Technol. Vol 55, pp:198-205.

Neelavannan M. G, Revathi M, Ahmed Basha C (2007), “Photocatalytic and Electrochemical Combined Treatment of Textile Wash Water”, Journal of Hazardous Materials, Vol: 149, pp: 371–378.

Peralta-Hernandez J M, Mendez-Tovar M, Guerra-Sanchez R, Martınez-Huitle C A, and Nava J (2012), “Review Article: A Brief Review on Environmental Application of Boron Doped Diamond Electrodes as aNew Way for Electrochemical Incineration of Synthetic Dyes”, Hindawi Publishing Corporation, International Journal of Electrochemistry, pp: 18, DOI: https://doi.org/10.1155/2012/154316

Prakash Kariyajanavar, Narayana Jogttappaa, Yanjerappa Arthoba Nayaka (2011), “Studies on Degradation of Reactive Textile Dyes Solutions by Electrochemical Method”, J. Hazardous Material, Vol: 190, pp: 952-961.

Rajkumar D, Byung Joo Song and Jong Guk Kim (2007), “Electrochemical Degradation of

Reactive Blue 19 in Chloride Medium for the Treatment of Textile Dyeing Wastewater with Identification of Intermediate Compounds”, Dyes and Pigments, Vol: 72, pp: 1-7.

Raju G B, Karuppiah M T, Latha S S, Parvathy S and Prabhakar S (2008), “Treatment of Wastewater from Synthetic Textile Industry by Electrocoagulation – Electro oxidation”, Chem Eng J., Vol: 144, pp:51–58.

Rezaee A, Ghaneian M T, Hashemian S J, Moussavi G, Khavanin A and Ghanizadeh G (2008), “Decolorization of Reactive Blue 19 Dye from Textile Wastewater by the UV/H2O2 Process”, J. Appl. Sci., Vol: 8, pp: 1108-1122.

Sheng H Lin and Chi F Peng (1994), “Treatment of Textile Wastewater by Electrochemical Method”, Wat.Res., Vol: 28, No: 2, pp: 277-282.

Shyamala Gowri R, Vijayaraghavan R and Meenambigai1 P, (2014), “Microbial degradation of Reactive Dyes- A Review”, Int. J. Curr. Microbiol. App. Sci, Vol: 3, pp: 421-436.

Downloads

Published

2018-03-19

How to Cite

Rekha, H. B., & Murthy, U. N. (2018). ELECTROCHEMICAL DEGRADATION OF REMAZOL RED RB 133 USING SACRIFICIAL ELECTRODES. MATTER: International Journal of Science and Technology, 4(1), 106–128. https://doi.org/10.20319/mijst.2018.41.106128