SUSTAINABLE REGENERATION OF MORDENITE MINERAL AS ION EXCHANGER FOR REMOVAL IRON AND MANGANESE IN GROUNDWATER

Authors

  • Elda Septiyani Department of Environmental Engineering, Faculty of Civil and Environmental Engineering, Bandung Institute of Technology, Bandung, Indonesia
  • Yuniati Zevi Department of Environmental Engineering, Faculty of Civil and Environmental Engineering, Bandung Institute of Technology, Bandung, Indonesia
  • Nur Novilina Arifianingsih Department of Environmental Engineering, Faculty of Civil and Environmental Engineering, Bandung Institute of Technology, Bandung, Indonesia

DOI:

https://doi.org/10.20319/mijst.2020.61.147160

Keywords:

Groundwater, Adsorption, Iron, Manganese, Mineral Mordenite, Regeneration, Thiobacillus Ferrooxidans

Abstract

Access to clean water is a basic need for humans. At present, groundwater quality is a fundamental consideration factor in its utilization. Metal removal in groundwater with filtering techniques has been done quite a lot with various media, one of which is zeolite. However, the pore blockage often becomes a problem, so it inhibits the process and shortens the life of the stone in adsorbing iron and manganese, to overcome this problem regeneration is needed so that Mordenite can be reused. This research aims to study the method of regeneration chemically and biologically so as to improve the ability of Mordenite in removing iron and manganese by using a continuous bed reactor with an up-flow system for 60 minutes. Activation and regeneration of Mordenite from natural zeolite is carried out chemically using NH4Cl by immersion method, while biological regeneration is carried out by utilizes Thiobacillus ferrooxidans bacteria. The removal efficiency obtained will decrease as the adsorbent is used. Efforts to increase the adsorption capacity will continue to be carried out by giving chemical and biological regeneration. Furthermore, adsorption capacity and removal efficiency in each variation of Mordenite mineral adsorbents are included in the scope of the research.

References

Agate, AD. 1996. Recent advances in microbial mining. World J Microbiol Biotechnol. 12:487–95. https://doi.org/10.1007/BF00419462

Aktas, Ö., Çeçen, F. 2007. Bioregeneration of activated carbon: a Review. Int. Biodeter. Biodegr. 59, 257–272. https://doi.org/10.1016/j.ibiod.2007.01.003

Barret J, Hughes MN, Karavaiko GI, Spencer PA. 1993. Metal Extraction by Bacterial Oxidation of Minerals. New York: Ellis Horwood.

De Jonge, R.J., Breure, A.M., van Andel, J.G., 1996. Bioregeneration of powdered activated carbon (PAC) loaded with aromatic compounds. Water Res. 30, 875– 882 https://doi.org/10.1016/0043-1354(95)00247-2

Demir, A. Günay, E. Debik. 2002. Ammonium removal from aqueous solution by ion-exchange using packed bed natural zeolite, Water SA. 28, 329–335. https://doi.org/10.4314/wsa.v28i3.4903

Dewita, Silvany. 2017. Penyisihan Besi dan Mangan dalam Air Tanah dengan Reaktor Kontinu Menggunakan Adsorpsi Mineral Modernite Aktivasi dan Alami. Teknik Lingkungan: Institut Teknologi Bandung.

Ehrlich HL, Brierley CL. 1990. Microbial Mineral Recovery. New York: McGraw Hill.

Fauziah, Adelina. 2010. Efektivitas Saringan Pasir Cepat Dalam Menurunkan Kadar Mangan (Mn) Pada Air Sumur Dengan Penambahan Kalium Permanganat (KMnO4) 1%. Skripsi FKM USU: Medan.

Febrina, Laila and Ayuna, Astrid. 2014. Studi Penurunan Kadar Besi (Fe) dan Mangan (Mn) dalam Air Tanah Menggunakan Saringan Keramik. Jurnal Teknologi Universitas Muhammadiyah Jakarta Volume 7 No.1.

Gamal, El Maisa., Mousa A. Hussein., El-Naas H. Muftah., Zacharia, Renju., Judd, Simon. 2018. Bio-regeneration of Activated Carbon: A Comparative Review. Journal of Separation Purification Technology. https://doi.org/10.1016/j.seppur.2018.01.015

Goel J, Kadirvelu K, Rajagopal C and Garg V. 2005. Removal of Lead (II) by Adsorption using Treated Granular Activated Carbon: Batch and Column Studies. Journal of Hazardous Materials 125; 211-220. https://doi.org/10.1016/j.jhazmat.2005.05.032

Heath, Ralph C. 2004. Basic Ground-Water Hydrology. U.S. Geological Water Survey-Supply Paper 2220 in Cooperation with The North Carolina Department of Natural Resources and Community Development. North Carolina, United States.

K.-H. Choo, H. Lee, S.-J. Choi. 2005. Iron and Manganese Removal and Membrane Fouling During UF in Conjunction with Pre-Chlorination for Drinking Water Treatment. Jounal. Membrane Science. 267 (1–2) 18–26. https://doi.org/10.1016/j.memsci.2005.05.021

Klimenko, N., Smolin, S., Grechanyk, S., Kofanov, V., Nevynna, L., Samoylenko, L. 2003. Bioregeneration of activated carbons by bacterial degraders after adsorption of surfactants from aqueous solutions. Colloids and Surfaces A 230, 141–158. https://doi.org/10.1016/j.colsurfa.2003.09.021

Larasati, Amanda. 2013. Penyisihan Besi dan Mangan dengan Menggunakan Air Bubble Reactor. Bandung: Tugas Akhir Program Studi Teknik Lingkungan ITB.

Leathen, W.W, N.A. Kinsel, and S.A. Braley. 1956. Ferrobacillus ferrooxidans: achemosynthetic autotrophic bacterium. J.Bacteriol., 72, 700¬704. https://doi.org/10.1128/JB.72.5.700-704.1956

Lee, K.M., Lim, P.E., 2005. Bioregeneration of powdered activated carbon in the treatment of alkyl-substituted phenolic compounds in simultaneous adsorption and biodegradation processes. Chemosphere 58, 407–426.https://doi.org/10.1016/j.chemosphere.2004.09.027

Lijzen, J.P., Otte, P., Van Dreumel, M. 2014. Towards Sustainable Management of groundwater: Policy Developments in The Netherlands. Sci. Total Environ. 485 – 486, 804 – 809. https://doi.org/10.1016/j.scitotenv.2014.02.081

Novandy, Deify. 2014. Studi Kinetika dan Kapasitas Adsorpsi Ion Mangan dan Besi pada Adsorben Mineral Mordenite dengan Sistem Batch. Bandung: Institut Teknologi Bandung.

Nurseha. 2000. Isolasi dan Uji Aktivitas Bakteri Asidofilik Pengoksidasi Besi dan Sulfur dari Ekosistem Air Hitam. Tesis, Program Pasca Sarjana, IPB. Bogor.

Opera, Camelia., Viorica Popescu., and Semaghiul Birghila. 2006. New Studies About the Modified Mordenite. Journal of Physics of Ovidius University, Constantia, Romania.

Orshansky, F., Narkis, N. 1997. Characteristics of organics removal by PACT simultaneous adsorption and biodegradation. Water Res. 31, 391–398. https://doi.org/10.1016/S0043-1354(96)00227-8

P. Thompson, N.W. Mbongwa, R. Rajagopaul, D.L. Gwebu, C. Van Der Merwe. 2016. The Evaluation of Biofiltration for the Removal of Iron and Manganese from Groundwater. http://ewisa.co.za/literature/files/

R. El Araby, S. Hawash, G. El Diwani. 2009. Treatment of Iron and Manganese in Simulated Groundwater via Ozone Technology. Desalination 249, 1345 – 1349. https://doi.org/10.1016/j.desal.2009.05.006

Rawlings DE, Silver S. 1995. Mining with microbes. Biotechnology; 13:773–8. https://doi.org/10.1038/nbt0895-773

Rawlings DE. 1998. Industrial practice and the biology of leaching of metals from ores. The 1997 Pan Labs lecture. J Ind Microbiol Biotechnol; 20:268–74. https://doi.org/10.1038/sj.jim.2900522

Rossi G. 1990. Biohydrometallurgy. Hamburg: McGraw Hill.

S. Astari, R. Iqbal. 2009. Kehandalan Saringan Pasir Lambat dalam Pengolahan Air. Undergraduate Thesis, Fakultas Teknik Sipil dan Lingkungan. Institut Teknologi Bandung, Indonesia.

Satria L. 2015. Penyisihan Ion Besi dan Mangan dengan Mineral Mordenite yang Diaktivasi dalam Fixed Bed Continuous Reactor. Thesis. Bandung: Institut Teknologi Bandung.

Sharma S. 2001. Adsorptive Iron Removal from Groundwater. UNESCO-IHE Institute for Water Education. Delft.

Silva, M., Fernandes, A., Mendes, A., Manaia, C.M., Nunes, O.C. 2004. Preliminary feasibility study for the use of an adsorption/bio regeneration system for molinate removal from effluents. Water Res. 38, 2677–2684. https://doi.org/10.1016/j.watres.2004.03.016

Sirotkin A.S., Ippolitov, K.G., Koshkina, L.Y. 2002. Bioregeneration of activated carbon in BAC filtration. In: Proceedings of Biological Activated Carbon Filtration IWA Workshop, 29–31 May 2002, Delft University of Technology, Delft, The Netherlands.

Sun, R., Jin, M., Giordano, M., Villholth, K.G. 2009. Urban and Rural Groundwater Use in Zhengzhou, China: Challenges in Joint Management. Hydrogeol. J. 17 (6), 1495 – 1506. https://doi.org/10.1007/s10040-009-0452-0

Syamsiah, S., Hadi, I.S. 2004. Adsorption cycles and effect of microbial population on phenol removal using natural zeolit. Sep. Purif. Technol. 34, 125–133. https://doi.org/10.1016/S1383-5866(03)00186-2

Z. Fu-wang, L. Xing, Y. Yan-ling. 2009. Study on The Effect of Mn (II) Removal with Oxidation and Coagulation Aid of Potassium Manganate. 3rd International Conference on Bioinformatics and Biomedical Engineering, Beijing, pp. 1–4.

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Published

2020-07-07

How to Cite

Septiyani, E., Zevi, Y., & Arifianingsih, N. N. (2020). SUSTAINABLE REGENERATION OF MORDENITE MINERAL AS ION EXCHANGER FOR REMOVAL IRON AND MANGANESE IN GROUNDWATER. MATTER: International Journal of Science and Technology, 6(1), 147–170. https://doi.org/10.20319/mijst.2020.61.147160